The first commercial PV solar product was nah just in 1909.
See story above, and original article in Modern Electrics magazine in 1909:
https://babel.hathitrust.org/cgi/pt?id=mdp.39015051407073
EDIT
Since people didn’t read past the headline, the article is about a startup company in 1905 that developed a commercial electrical solar panel by 1909 and was worth 160 million in today’s money.
In 1909, the inventor of the solar panel was kidnapped and ordered by his kidnappers to destroy all information about this solar panel. He was eventually released, although he did not destroy the solar panel or his documentation, he did shut down his company.
So this is a pretty fascinating development considering that at this time period we actually did have early production electric cars that were manufactured in larger quantities than gas vehicles, and now we learn that solar panels were commercially available, at least for a short time.
And the solar panels could generate a fair amount of electricity:
500 volts per 10 square ft, and a smaller demonstration panel that was 3 ft x 4 ft could generate 60 watts of power (10 volts @6 amps).
Additionally, the panels were designed to charge a battery backup system.
These solar panels must have been using some older technology fundamentally different from the one used in current solar panels because the PN junction, basis of the photocell, was not invented until 1939
Likey also didn’t contain rare earth minerals - no where near as effective but could have been less damaging and easier to make.
Then again, could have been a combination of arsenic, asbestos and cocaine so who knows.
I want to read more about this, as there is some speculation that the guy may have invented an actual PV panel. Difficult to say without more research… He was also a prolific inventor.